Heterobimetallic Aryloxides of Titanatranes with Aluminum Alkyls for Ring opening polymerization (ROP) of rac-Lactide (AOICS) - Lupine Publishers

Heterobimetallic Aryloxides of Titanatranes with Aluminum Alkyls for Ring opening polymerization (ROP) of rac-Lactide (AOICS) - Lupine Publishers

The titanatrane titanium complexes were treated with Aluminum Alkyls to prepare their bimetallic derivatives (1a-4a). The compounds were confirmed by means of NMR and elemental analysis. The complexes were used as catalysts for ring opening polymerization of racemic lactide. The complexes exhibit high activity and selectivity in the polymerization process.

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